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Molecular Compounds

View larger. Quantity This product is not sold individually. Crystallisable polymers for the past 60 years.

Molecular compounds from crystallisable polymers, particularly from small molecules. The present book gives a detailed description of these promising systems. The first chapter is devoted to the presentation of important investigational techniques and some theoretical approaches.

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As a general rule, the solubility parameters of polymers do not change much with temperature, whereas those of low molecular weight compounds often decrease noticeably with increasing temperature. In some cases, a solvent passes through soluble conditions to once more to become a non-solvent as the temperature increases.

PDF Polymer-Solvent Molecular Compounds

Solubility parameters are frequently used in the paint and coating industry to aid in the selection of solvents and to predict the compatibility of polymers. Compounds with similar chemical structure are more prone to dissolve than those with dissimilar structure.

As a general rule, the lower the molecular weight of a polymer, the greater its solubility in a solvent. The higher the molecular weight of a polymer, the closer the solubility parameter of the solvent needs to be to dissolve the polymer in the solvent.


Polymer Solubility and Solubility Parameter Solubility parameters were initially developed to guide solvent selection in the paint and coatings industry. Note that this equation always predicts positive heats of mixing which is only true for regular solutions.


Theromophysical Data Key data on over two hundred and fifty polymers. Polymers Index. Typical Performance Properties of commercial commodity and engineering polymers.